High oxidation state aqueous organometallics.: Formation and structure of an oxo-centred Cp* MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

Demirhan, FGun, JLev, OModestov, APoli, RRichard, P2024-07-182024-07-181472-7773http://akademikarsiv.cbu.edu.tr:4000/handle/123456789/7718Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4 (O2CCF3)(3)](+) and [Zn-2(O2CCF3)(6)](2-) ions after crystallisation from THF-Et2O.EnglishM = MOCLUSTER ELECTRONSX-RAYCOMPLEXESMOLYBDENUMOXIDESCONVENIENTHigh oxidation state aqueous organometallics.: Formation and structure of an oxo-centred Cp* MoV trinuclear cation by chemical reduction of Cp*2Mo2O5Article