Özbek, HAKopar, EEDemirhan, F2024-07-182024-07-180095-89721029-0389http://akademikarsiv.cbu.edu.tr:4000/handle/123456789/7914A series of Lindqvist-type polyoxometalate (POM) compounds [Cat][Cp*2M5VO17] (M = Mo (1), W (2)) were obtained from Cp*2M2O5 and NaVO3 in a 1:10 molar ratio in an acidic aqueous-methanol medium ([Cat]: Bu4P+ (1a, 2a), Bu4N+ (1b, 2b), Ph4P+ (1c, 2c), and BuNC5H5+ (1d, 2d)). They have been structurally characterized by H-1 and P-31 NMR, FT-IR, TGA, ESI, and elemental analysis techniques which support the proposed structures. In antibacterial studies, Ph4P[Cp*2Mo5VO17] (1c) is the compound that shows the highest antimicrobial activity against both gram-positive and gram-negativebacteria.EnglishHIRSHFELD SURFACE-ANALYSISCRYSTAL-STRUCTUREVIBRATIONAL INVESTIGATIONSHYDROTHERMAL SYNTHESISFACE INTERACTIONSOXO-CLUSTERSLINDQVISTEPOXIDATIONCOMPOUNDSUBSTITUTIONArticle