Sözerli S.E.Özen A.Kani I.Demir D.2024-07-222024-07-22201413000527http://akademikarsiv.cbu.edu.tr:4000/handle/123456789/16997A novel [Pb2(μ-atrz) 2(μ-CH3 COO)(CH 3 COO)]n (atrz = 3-amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecularstructure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2). © TÜBİTAK.EnglishAll Open Access; Bronze Open AccessArticle10.3906/kim-1308-19