Dinoi C.Taban G.Sözen P.Demirhan F.Daran J.-C.Poli R.2024-07-222024-07-2220070022328Xhttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/19211Use of aqueous conditions and the ROOH (R = tBu or H) compounds as oxidizing agents affords a simple two-step, one-pot synthetic procedure leading to [Cp2* M2 O5] (M = Mo, W) from [M(CO)6] selectively and in high yields. The hexacarbonyl compounds are converted to Na[Cp*M(CO)3] in refluxing THF, then the mixture is diluted with water (W) or aqueous NaOH (Mo) and directly treated with 6 equiv. of ROOH. Acidification of an aqueous solution of the Na[Cp*MO3] product affords spectroscopically pure [Cp2* M2 O5] in high isolated yields (global yields from [M(CO)6], for R = tBu: Mo, 91%; W, 87%). The X-ray structures of Na[Cp*MoO3] · 5H2O and [Cp2* W2 O5] are also reported. © 2007 Elsevier B.V. All rights reserved.EnglishAll Open Access; Green Open AccessLigandsMolecular structureOrganometallicsSolutionsSynthesis (chemical)Tungsten compoundsWaterX ray analysisAqueous organometallic chemistryOxo ligandsPentamethylcyclopentadienyl ligandsX ray structuresMolybdenum compoundsArticle10.1016/j.jorganchem.2007.05.021