Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10phen)(OH)x]3[Cr(OH)6Mo6O18]•16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)

Özbek Avci H.2024-07-222024-07-22202321490120http://akademikarsiv.cbu.edu.tr:4000/handle/123456789/12053Five new Anderson-type polyoxometalate compounds [M((1,10-phen) (OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3),Ni(4),Cu(5);x=1,2) were obtained from Na2MoO42H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-. © 2023, Turkish Chemical Society. All rights reserved.EnglishAll Open Access; Gold Open Access; Green Open AccessSynthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10phen)(OH)x]3[Cr(OH)6Mo6O18]•16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)Article10.18596/jotcsa.1215066