Browsing by Author "Souadi, G"
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Item Anomalous heating rate dependence and analyses of thermoluminescence glow curves in Gd doped ZnB2O4 phosphorsAtasoz, S; Topaksu, M; Souadi, G; Can, NHere, we report the thermoluminescence (TL) characteristics and trapping parameters under beta ray excitations of pelletized Gd-incorporated ZnB2O4 synthesized through the gel combustion method. The chemical composition of the obtained Gd incorporated ZnB2O4 was confirmed using X-ray diffraction (XRD). The best doping concentration of Gd was 0.25 mass%, which resulted in the highest luminous efficiency. The glow curves of the pellet-formed samples exposed to beta-irradiation at various doses showed glow peaks at about 79 degrees C, 133 degrees C and 276 degrees C with a heating rate of 2 degrees Cs-1. An anomalous heating rate effect was observed for the peak centered at 276 degrees C, but the TL intensity of the peak at 79 degrees C and 133 degrees C decreased with an increasing heating rate. The TL glow peaks were studied using T-m-T-stop, initial rise (IR), and variable heating rate (VHR) and Computerized glow curve deconvolution (CGCD) methods. In the range of 0.1-50 Gy, the total integral values of TL output increased linearly with increased dose. A complex glow curves are composed of six distinguishable peaks as revealed by the results obtained from IR and CGCD methods. The current results indicate that the ZnB2O4:Gd3+ phosphor is a suitable option in radiation dosimetry for environmental monitoring.Item Luminescence of undoped and Eu3+activated zinc gallate phosphor: Synthesis, unusual intense 5D0 → 7F4 red emissionSouadi, G; Kaynar, ÜH; Ayvacikli, M; Can, NA series of Eu3+-doped ZnGa2O4 samples were synthesized via the urea-glycine combustion route. Powder X-ray diffraction (XRD) was used to investigate the crystallinity of the samples, energy dispersive spectroscopy (EDS) to explore the elemental composition, Fourier transform infrared (FTIR), to observe the vibrational modes of the samples, photoluminescence (PL) to determine the luminescence properties. The XRD data prove that the samples remain single cubic structure even at high concentrations of Eu3+, enabling the formation of a unique emission spectrum. The active ion concentration was varied to examine the influence of concentration on luminescent properties. This study revealed a 5D0 & RARR;7F4 transition located at 700 nm with unusual intensity that has not been documented in the literature, which suggests that the active ion concentration can influence the luminescent characteristics of the phosphors. The increasing Eu3+ content increases the number of Eu3+ ions in ZnGa2O4 host lattice, which enhances the luminescence efficiency of the phosphor. However, beyond a certain level of Eu3+content (i.e., 3 wt% Eu3+), the number of Eu3+ ions becomes excessive, resulting in a reduction in luminescence efficiency due to concentration quenching. The dipole dipole interaction is elucidated to play a prominent role in the mechanism of Eu3+ quenching in the ZnGa2O4. An assessment of color coordinates based on emission spectra reveals that the coordinates shift from blue to the white light region, and then to red as Eu3+ content increases. This suggests that there is a substantial relationship between the Eu3+ concentration and the measured color coordinates.Item Thermoluminescence study and trapping parameters of beta irradiated NaBaBO3:Gd3+ phosphorOglakci, M; Topaksu, M; Souadi, G; Can, NA series of Gd3+ doped NaBaBO3 phosphors were synthesized via a combustion approach. The TL data collected by means of a combination of a commercial SCHOTT BG39 and HC414/46 filters was studied to evaluate basic kinetic parameters. Tm-Tstop and, various heating rate (VHR) and computerized glow-curve deconvolution analyses were utilized to analyze collected data. Our findings indicate that luminescence process in scrutinized material may obey first-order kinetics because no shift in the experimental TL glow curves with increased dose was observed. The TL dose response of the TL glow peaks exhibited a linear characteristic up to 20 Gy. The TmTstop method revealed that the number of the component TL glow peaks in the complex glow curve with and without preheating process consisted of six well-isolated and three overlapping glow peaks, respectively. The number of peaks obtained by deconvolution was perfectly matched with those obtained by Tm-Tstop and the figure of merit (FOM) values with and without preheating were 0.84% and 1.48%, respectively. The activation energy value found for the peak at 312 degrees C using the various heating rate (VHR) method was very close to those of deconvolution method. The total loss of response of TL glow curve sensitivity was much less (only +/- 2%) after 10 cycles of reuse.Item Novel Sm3+doped YCa4O(BO3)3 phosphors: Structural and, low and room temperature luminescent insightsSouadi, G; Amri, N; Kaynar, ÜH; Coban, MB; Madkhali, O; Ayvacikli, M; Can, NInorganic phosphors, known for their ability to capture energy from various sources and emit visible light, have become essential in the development of advanced lighting and display technologies. This study explores YCa4O (BO3)3 (YCOB) as a potential host material for phosphors, focusing on the luminescent properties of YCOB phosphors doped with Sm3+ ions. The successful integration of Sm3+ ions into the YCOB host lattice is confirmed through structural characterization using X-ray diffraction (XRD), Fourier -Transform Infrared Spectroscopy (FTIR), and Energy -Dispersive X-ray Spectroscopy (EDS). Photoluminescence (PL) studies reveal distinct emission spectra with Stark energy level splitting, indicating a cooperative effect between Y3+ and Sm3+ ions. Concentration quenching, mainly attributed to dipole -dipole (d -q) interactions, is observed at higher Sm3+ concentrations. Temperature -dependent PL measurements demonstrate thermal quenching at lower temperatures and increased emission intensity with higher laser power. Thermal quenching is explained by reduced lattice vibrations and electron -phonon interactions, leading to decreased radiative recombination of charge carriers. The CIE chromaticity data position the samples in the orange -red region, emitting vibrant orange -red light. This comprehensive investigation provides insights into the synthesis and luminescent properties of YCOB:Sm3+ phosphors, highlighting their potential applications in luminescent devices.Item Synthesis and beta particle excited thermoluminescence of BaSiF6 phosphorSouadi, G; Akca-Ozalp, S; Karali, EE; Kaynar, UH; Ayvacikli, M; Topaksu, M; Can, NBaSiF6 phosphor was synthesized by a gel combustion method. The crystalline size was found to be 54.17 +/- 4.36 nm using Williamson-Hall (W-H) approximation. The TL data collected by means of a combination of a commercial BG39 and HC575/25 filters was studied to evaluate basic kinetic parameters. Three TL glow peaks of BaSiF6 phosphors are centered at around 84, 190 and 322 degrees C. T-m-T-stop, various heating rate (VHR) and computerized glow-curve deconvolution (CGCD) method were utilized to analyse collected data. Our findings indicate that luminescence process in scrutinized material may obey second order kinetics. The TL dose response of the TL glow peaks exhibits a linear characteristic up to 100 Gy. Deconvolution of the glow curve reveals that the number of the component TL glow peaks in the complex glow curve is composed of well-isolated six overlapping glow peaks. The FOM value is 2.32.Item Tb-doped MgAl2O4 phosphors: A study of structural and luminescence characteristicsHalefoglu, YZ; Souadi, G; Ayvacikli, M; Bulcar, K; Topaksu, M; Canimoglu, A; Madkhali, O; Karmouch, R; Can, NIn the MgO-Al2O3 system, magnesium aluminate spinel (MgAl2O4) is a technologically significant compound due to its unique properties, including a high melting point, low thermal conductivity, excellent thermal shock resistance, chemical inertness, and robust mechanical strength. This compound has diverse applications in re-fractory materials, catalyst supports, moisture sensors, nuclear techniques, insulating materials, and even mili-tary applications. While rare-earth elements are commonly used as dopants in luminescent materials, limited research exists on doping of Tb3+ ions in magnesium aluminate. This study investigates the luminescence properties of Tb3+ doped synthesis magnesium aluminate materials, shedding light on this underexplored area. The combustion method is employed for synthesis, known for producing nano-sized powders with exceptional luminescent properties. Additionally, this study explores Sm3+ ion doping in magnesium aluminate materials and their luminescence properties. Using the combustion synthesis method, structural attributes of Tb3+-doped MgAl2O4 nanophosphors are meticulously examined. Through X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) analyses, coupled with excitation and emission spectra, a comprehensive investigation of the luminescent provide behavior at room temperature is provided. The XRD data reveal Tb3+ doped MgAl2O4 phosphors exhibit a single phase with face centred cubic structure belonging to the Fd3 m space group, consistent with the standard JCPDS files (No. 21-1152). Excitation and emission spectra offer valuable insights into the energy transitions within the Tb3+-doped MgAl2O4 phosphors. Furthermore, the study explores the effects of varying Tb3+ ion concentrations on the luminescent properties, revealing an optimal doping concentration of 5 wt% Tb for maximizing emission intensity. Concentration quenching, primarily attributed to dipole-dipole (d-q) interactions, is observed at higher Sm3+ concentrations. In conclusion, this research enhances our understanding of rare-earth ion doping in luminescent materials and highlights the potential applications of Tb3+-doped MgAl2O4 nanophosphors, which offer promise for various technological applications, including lighting and displays.Item Synthesis and photoluminescence characteristics of a novel Eu and Tb doped Li2MoO4 phosphorSouadi, G; Kaynar, UH; Ayvacikli, M; Coban, MB; Oglakci, M; Canimoglu, A; Can, NLi2MoO4:x Eu3+ and Li2MoO4:xTb(3+) phosphors, where x = 0.5, 1, 2, 3, 5 and 7 wt%, were synthesized through a gel-combustion method. The XRD data reveals that Eu3+ and Tb3+ doped Li2MoO4 phosphors exhibit a Rhombohedral structure belonging to the space group R3 which matched well with the standard JCPDS files (No.0120763). We present photoluminescence (PL) spectra from Eu and Tb doped Li2MoO4 under 349 nm Nd:YLF pulses laser excitation over the temperature range of 10-300 K. Undoped Li2MoO4 shows a wide broad band around 600 nm because of the intrinsic PL emission of tetrahedral of MoO42- which was in good agreement with previous findings. Under the excitation of 394 nm, the as-synthesized phosphors exhibited sharp and strong intensity PL emission signals in the red (612 nm, D-5(0) -> F-7(2) transition) and green (544 nm, D-5(4) -> F-7(5) transition), respectively. The critical doping concentration of Eu3+ and Tb3+ ions in the Li2MoO4 were estimated to be 2 wt%. The concentration quenching phenomena were discussed, and the critical distances for energy transfer have also been evaluated by the concentration quenching.Item Anomalous dose behaviour of thermoluminescence glow curves and kinetic analysis of beta irradiated YAl3(BO3)4:Tb phosphorSouadi, G; Bulcar, K; Kaynar, UH; Ayvacikli, M; Topaksu, M; Cam-Kaynar, S; Can, NWith the aid of thermoluminescence (TL), we have extensively studied YAl3(BO3)4 host matrices incorporated with Tb3+ at different doping contents, which have been produced by combustion. The measured the TL glow curves exposed to beta rays at different doses consisted of four broad peaks located at around 76, 126, 230, and 378 degrees C. The peak maximum of the 230 degrees C TL peak shifts toward higher temperatures after 5 Gy beta irradiation while the other peak maxima almost remain constant. It is peculiar that 230 degrees C peak maximum shifts to higher temperatures with increased radiation dose and can be attributed to the multiple phases of the sample. A TL glow curve exhibits a proportional increase in intensity with increased the heating rate. A discussion of the possible causes of this pattern is provided. Observed peaks using the TmTstop method are due to the presence of a quasicontinuous distribution of traps. The parameters of the traps have also been estimated using various heating rate methods in excellent agreement with one another.Item Thermoluminescence characteristics of a novel Li2MoO4 phosphor: Heating rate, dose response and kinetic parametersSouadi, G; Kaynar, UH; Oglakci, M; Sonsuz, M; Ayvacikli, M; Topaksu, M; Canimoglu, A; Can, NLithium molybdate (Li2MoO4) phosphor was synthesized by a gel combustion method and its thermoluminescence properties were studied with the irradiation of beta. Various Heating Rate (VHR), Initial Rise (IR), and Computerized Glow Curve Deconvolution (CGCD) methods were used to determine the kinetic parameters (activation energy E (eV), frequency factor s (s(-1)), and kinetic order b) of the visible glow peaks. According to the kinetic study, the TL glow curve is made up of seven separate peaks with activation energies of 1.05, 0.76, 0.40, 0.60, 0.78, 1.81 and 1.25 eV and these peaks follow general-order kinetics. The results clearly showed that undoped Li2MoO4 has a potential to be considered in dosimetric applications where high doses have to be monitored as in the case of clinical dosimetry.Item Characterization of thermoluminescence kinetic parameters of beta irradiated B doped Ca5(PO4)3OH powder obtained from eggshellDepci, T; Oglakci, M; Sezer, S; Yücel, A; Dogan, T; Souadi, G; Topaksu, M; Can, NIn this study, we have synthesized B doped Ca5(PO4)3OH (HAP) by a sonication chemical method. The thermoluminescence (TL) properties of the family of synthesized samples (B doped Ca5(PO4)3OH (HAP) were investigated using an IRSL-TL 565 nm filter. This gave the highest TL intensity of each phosphor after 2 Gy beta-irradiation. Three TL glow peaks of B doped Ca5(PO4)3OH (HAP) are centered at around 84, 208 and 324 degrees C (with a heating rate of 2 degrees Cs-1). The trapping parameters such as activation energy (E), order of kinetics (b), frequency factor (s) were calculated by using initial rise (IR), various heating rates (VHR) and computerized glow curve deconvolution (CGCD) method. The response of TL glow curves remained constant within +/- 5% deviation from the initial value after 9 cycles of reuse; but only at tenth cycle the deviation goes up to 6%.Item Thermoluminescence glow curve analysis and evaluation of trapping parameters of dysprosium doped lanthanum calcium borate La2CaB10O19Bulcar, K; Oglakci, M; Kaynar, UH; Ayvacikli, M; Souadi, G; Topaksu, M; Can, NThe present work elucidates thermoluminescence study of Dy activated lanthanum calcium borate (La2CaB10O19) phosphors and determination of trapping parameters. Two glow curves located at 132 and 295 degrees C were observed and showed a linear TL response. The kinetic parameters of the glow peaks were evaluated using variable heating rate, repeated initial rise method and Computerized Glow Curve Deconvolution. Analysis of the main dosimetric peaks reveals that the values of the activation energy and pre-exponential factor are found to be 0.78-1.145 eV and 8.59 x 10(9)-8.44 x 10(11) s(-1), respectively. The sample doped with 1% Dy3+ exhibits a good stability for the reusability. Besides, the found results indicate that the temperature maximum shifts to the higher temperature side as the heating rate increases. Contrary to previously expressed theoretical expectations, anomalous heating rate dependence was observed in Dy3+ doped La2CaB10O19 sample and a semi-localized transition model explaining the anomalous heating rate effect was employed.Item Beta irradiation-induced thermoluminescence: Glow curve analysis and kinetic parameters in combustion-synthesized undoped Ca4YO(BO3)3Madkhli, AY; Jabali, DA; Souadi, G; Sonsuz, M; Kaynar, UH; Akça-Özalp, S; Ayvacikli, M; Madkhali, O; Topaksu, M; Can, NThis study examines the thermoluminescent (TL) properties of undoped Ca4YO(BO3)3 phosphor, focusing on how it behaves under a variety of experimental conditions. The IRSL-TL 565 nm was chosen as the appropriate detection filter among various optical detection filter combinations. During the preheating trials conducted at a rate of 2 degrees C/s, the TL peak exhibited increased intensity, particularly around 200 degrees C. The experimental outcomes demonstrated a reliable linear relationship (R2 = 0.996 and b = 1.015) in the dose response of undoped preheated Ca4YO(BO3)3 within the range of 1-200 Gy. The investigation encompasses a range of techniques, including the TM-Tstop method, computerized glow curve deconvolution (CGCD) analysis, and theoretical modelling. The application of the TM-Tstop method to samples irradiated with a 5 Gy dose revealed distinct zones on the TM versus Tstop diagram, signifying the presence of at least two discernible components within the TL glow curve, specifically, a single general order kinetics peak and a continuous distribution. The analysis of activation energy versus preheated temperature exhibited a stepwise curve, indicating five trap levels with depths ranging between 1.13 eV and 1.40 eV. The CGCD method also revealed the superposition of at least five distinct TL glow peaks. It was observed that their activation energies were consistent with the Tm-Tstop experiment. Furthermore, the low Figure of Merit (FOM) value of 1.18% indicates high reliability in the goodness-of-fit measure. These findings affirm the reliability and effectiveness of the employed methods in characterizing the TL properties of the Ca4YO(BO3)3 phosphor under investigation. Theoretical models, including the semi-localized transition model, were introduced to explain anomalous observations in TL glow peak intensities and heating rate patterns. While providing a conceptual framework, these models may require adjustments to accurately capture the specific characteristics uncovered through CGCD analysis. As a potential application, the study suggests that the characterized TL properties of Ca4YO(BO3)3 phosphor could be utilized in dosimetric applications, such as radiation dose measurements, owing to its reliable linear response within a broad dose range.Item Synthesis and enhanced photoluminescence of the BaSiF6:Dy3+ phosphors by Li+ doping via combustion methodSouadi, G; Kaynar, UH; Ayvacikli, M; Canimoglu, A; Can, NUndoped BaSiF6, Dy3+ doped BaSiF6, and Dy3+, Li+ co-doped BaSiF6 phosphors were synthesized through a gelcombustion method. The prepared samples were characterized by powder x-ray diffraction (XRD), Fourier transform infrared (FTIR), energy dispersive x-ray spectroscopy (EDS), and photoluminescence (PL) techniques. The XRD data revealed that both the Dy3+ doped and Li+ co-doped BaSiF6 phosphors exhibited a single-phase structure belonging to the space group R (3m) over bar which matched well with the standard JCPDS files (No. 002-6613). FTIR spectra showed absorption bands at 3417 cm -1 , 1640 cm(-1), and 1620 cm(-1) corresponding to water molecules. EDS analysis confirmed the chemical composition of the prepared samples. The PL emission spectra of BaSiF6:Dy3+ by different co-doping concentrations of Li+ exhibited prominent emission peaks at 490 nm, 572 nm, 672 nm and 758 nm. The incorporation of Li+ is beneficial for enhancing the photoluminescence intensity. The optimum Li+ amount was 8% for BaSiF6:Dy3+ and then started to decrease. The enhancement could be due to the occurrence of oxygen vacancies due to the incorporation of Li+ ions. The x = 0.301 and y = 0.361 coordinates of this phosphor with varying Li+ dopant concentration determined by the Commission Internationale de l'Eclairage (CIE - 1931) were in the white range. The present work demonstrates how a simple and effective method can be used to prepare novel nanophosphors for applications in the field of visible light emitting devices with enhanced white emission.Item Unravelling the impact of unusual heating rate, dose-response and trap parameters on the thermoluminescence of Sm3+activated GdAl3(BO3)4 phosphors exposed to beta particle irradiationSouadi, G; Kaynar, ÜH; Sonsuz, M; Akça-Özalp, S; Ayvacikli, M; Topaksu, M; Ozmen, OT; Can, NThe thermoluminescence of GdAl3(BO3)4 (GAB) doped with various concentrations of Sm3+ (i.e. from 0.5 to 7 wt %), prepared by gel combustion, was studied. TL glow peaks at 78 degrees C and 225 degrees C are observed. The intensity of the glow peak at 225 degrees C increased with a faster heating rate. To gain insight into the trap activation energies, the methods of Hoogenstraaten and Booth-Bohun-Parfianovitch were used, where the calculated activation energies are 0.57 eV and 0.60 eV for Peak I and 1.69 eV and 1.71 eV for Peak II respectively. The dose-response of GAB:0.5 wt%Sm3+ demonstrates robust linearity up to 40 Gy, with a strong correlation coefficient of 0.999. Both TM-Tstop combined with the Initial Rise (IR) and Computerized Glow Curve Deconvolution (CGCD) techniques were employed, which revealed six overlapping glow peaks beneath the main peaks. Additionally, the results suggest that the TL signal can be efficiently exploited for radiation dosimetry applications.Item Synthesis, characterization and enhanced photoluminescence and temperature dependence of ZrO2:Dy3+phosphors upon incorporation of K plus ionsCan, N; Coban, MB; Souadi, G; Kaynar, ÜH; Ayvacikli, M; Guinea, JG; Karali, EEThis study reports the successful synthesis and comprehensive characterization of ZrO2:Dy3+ phosphors with the incorporation of K+ ions. The introduction of Dy3+ and K+ in the ZrO2 lattice as lanthanide activators demonstrates its potential as an efficient host material. The structural integrity of ZrO2 remains unaltered following the doping process. Fourier-transform infrared spectroscopy (FTIR) analysis confirms the presence of Zr-O and O-H stretching, along with H2O bending modes in the phosphor sample. The wide luminescence band seen at 460 nm is attributed to luminescence defects in the ZrO2 induced by oxygen, and the presence of water molecules. Photoluminescence (PL) spectra analysis reveals pronounced emission peaks at 491 and 578 nm, corresponding to 4F9/2 -> 6H15/2 and 4F9/2 -> 6H13/2 transitions, respectively, upon excitation at 349 nm. Optimizing the Dy3+ doping concentration to 0.4 wt% and achieving a critical distance of 31.82 angstrom resulted in efficient energy transfer. Notably, co-doping K+ as a charge compensator significantly enhances the luminescence intensity. Moreover, at lower temperatures, direct excitation of Dy3+ ions through our pump wavelength, coupled with exciton-mediated energy transfer, leads to a remarkable increase in PL intensity. Tailoring the doping concentrations effectively shifts the emission spectrum of the phosphor mixture, aligning with the standard white light illumination co-ordinates (0.333, 0.333). This property positions the material as a promising candidate for applications in white light-emitting diodes (WLEDs) and various high-quality lighting applications. The enhanced photoluminescence and temperature dependence observed in ZrO2:Dy3+ phosphors upon the incorporation of K+ ions pave the way for their potential utilization in advanced luminescent devices.Item Thermoluminescence glow curve analysis and kinetic parameters of Eu doped Li2MoO4 ceramic phosphorsSouadi, G; Oglakci, M; Kaynar, UH; Correcher, V; Benavente, JF; Bulcar, K; Ayvacikli, M; Hiziroglu, A; Topaksu, M; Can, N; Karali, EELiMoO4: x Eu ceramic phosphors with x = 0.5, 1, 2, 3, 5, and 7 mol% were synthesized using a gel combustion method. X-ray diffraction (XRD) measurements confirmed a rhombohedral structure (space group R-3) of synthesized compounds. Following irradiation with 50 Gy beta dose, the sample doped with 5 mol% Eu exhibited the highest integrated thermoluminescence (TL) intensity. In order to evaluate dose-response, samples were irradiated with beta radiation for 10-1000 Gy. TL intensity with 1000 Gy dose without saturation yielded the highest integrated value. Different methods were employed to determine the number of peaks, the trap structure, and the kinetic parameters of the thermoluminescence glow curve of Eu doped Li2MoO4: the Hoogenstraaten method, the Booth-Bohun-Parfianovitch method, the initial rise method (IR), combined with the T-M-T-stop experiment, various heating rates (VHR), and glow curve fitting with two different software packages. Based on the glow curve deconvolution obtained using both software packages, the component TL glow peaks present in the complex glow curve are composed of well-isolated nine overlapping glow peaks. Two software packages have shown quite similar activation energies and frequency factors.Item Photoluminescence properties and structural analysis of Tb3+-doped K3Gd (BO2)6: A first study on negative thermal quenchingSouadi, G; Madkhli, AY; Kaynar, UH; Gok, C; Aydin, H; Coban, MB; Kaynar, SC; Ayvacikli, M; Can, NIn this study, Tb3+-doped K3Gd(BO2)6 phosphors were synthesized using the microwave-assisted sol-gel method to explore their photoluminescence (PL) properties and thermal stability. XRD and Rietveld refinement confirmed the incorporation of Tb3+ions, without secondary phases. PL analysis revealed a strong green emission near 542 nm, attributed to the 5 D 4 -> 7 F 5 transition of Tb3+ions. An optimal Tb3+concentration of 3 wt% was identified, beyond which concentration quenching significantly reduced luminescence intensity. Radiative energy transfer, occurring via reabsorption, was observed at lower concentrations, facilitating efficient energy migration. Conversely, at higher concentrations, non-radiative processes such as cross-relaxation dominated. Remarkably, negative thermal quenching (NTQ) was observed up to 470 K, with an activation energy of 0.96 eV. Additionally, Na+ co- doping introduced lattice distortions that enhanced energy transfer between Tb3+ions and improved luminescence efficiency. The chromaticity diagram highlighted a shift towards the yellow-green region with increasing the Tb3+concentration, demonstrating tunable emission properties for solid-state lighting applications.Item High temperature photoluminescence dependence and energy migration of Tb3+-Incorporated K3Y(BO2)6 phosphorsSouadi, G; Hakami, O; Kaynar, UH; Coban, MB; Aydin, H; Madkhali, O; Zelai, T; Ayvacikli, M; Can, NThis study investigates the structural and photoluminescence (PL) characteristics of Tb3+-incorporated K3Y(BO2)(6) (KYBO) phosphors synthesized via a microwave-assisted sol-gel technique. X-ray diffraction (XRD) and Rietveld refinement confirmed the formation of a pure hexagonal phase, with lattice expansion due to Tb3+ doping. PL studies revealed strong green emissions centered at 541 nm, attributed to the D-5(4) -> F-7(5) transitions of Tb3+ ions, with the highest intensity observed at 5 wt% Tb3+. A decrease in emission was observed at higher concentrations due to concentration quenching. Temperature-dependent PL measurements revealed reverse thermal quenching enhancing PL intensity. Chromaticity analysis based on CIE 1931 coordinates showed stable green emission across all concentrations, with a maximum color purity of 89.74% observed for the KYBO:3 wt% Tb3+ sample. The results, along with reverse thermal quenching behavior observed between 470K and 550K, suggest that these phosphors exhibit excellent potential for lighting and display technologies.Item Temperature-responsive insights: Investigating Eu3+and Dy3+activated yttrium calcium oxyborate phosphors for structure and luminescenceJabali, DA; Madkhli, AY; Souadi, G; Kaynar, UH; Coban, MB; Madkhali, O; Ayvacikli, M; Amri, N; Can, NAn investigation into the luminescent behavior of YCOB (Yttrium Calcium Oxyborate) doped with Eu3+ and Dy3+ ions, synthesized via the combustion method, is presented. The study, employing X-ray diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR), and Energy-Dispersive X-ray Spectroscopy (EDS) analyses, confirms the structural integrity and purity of the synthesized nanophosphors. An XRD pattern exhibiting distinct crystalline peaks indicates that the dopant ions were successfully integrated into the YCOB lattice. The photoluminescence (PL) response of YCOB with Eu3+ and Dy3+ ions is thoroughly examined, uncovering distinct excitation and emission spectra. In the case of Eu3+ doping, excitation spectra reveal a significant charge transfer (CT) band at 254 nm, indicative of electron transfer between oxygen and europium ions. This CT transition enhances our understanding of the excitation behavior, with the dominant and Laporte-forbidden 5D0 -> 7F2 transition. Characteristic peaks at 345 nm in the excitation spectra efficiently stimulate YCOB:Dy3+ when Dy3+ is used as a dopant. The primary emission peak at 585 nm corresponds to the hypersensitive electric dipole transition 4F9/2-6H13/2. Concentration quenching phenomena are observed, with a maximum Eu3+ concentration of 7 wt % attributed to the dipole-quadrupole interaction. Dy3+ doping, with a maximum concentration of 2 wt % primarily shows multipolar interactions, especially dipole-dipole interactions. The study extends to CIE chromaticity analysis, emphasizing Eu3+ doping's suitability for white light-emitting diode (WLED) applications and ensuring color stability. Conversely, varying Dy3+ concentrations do not yield consistent chromaticity coordinates. These findings have significant implications for the development of advanced phosphor materials across diverse applications, offering a roadmap for optimizing their optical performance.