Electrochemical deposition and behavior of mixed-valent molybdenum oxide film at glassy carbon and ITO electrodes
No Thumbnail Available
Date
2013
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
The effect of solution composition and the type of the anionic species on the electrochemical formation of mixed-valent molybdenum oxide on a glassy carbon and ITO electrode surfaces was elucidated. Susccessive recording of the voltammograms has shown that anionic species display different stabilizing effect on the reductive formation of hydrogen molybdenum bronzes [MoO 3-x (OH) x ] and chloroacetic acid buffer has given the best results. The deposit was built upon cycling the potential between 0 and -0.9 V (vs. Ag/AgCl) via reduction of Mo(VI) to Mo(V) on the electrode surface in pH 3.0 chloroacetic acid solution. Electrochemical impedance measurements carried out in this medium revealed a shift in potential zero charge values from -0.2 V to -0.55 V after the potential of the GCE had been cycled for 30 min. An establishment of mixed-valent molybdenum oxide deposit by time on the gold electrode surface was proved by quartz crystal microbalance measurements. Atomic force and scanning electron microscopy techniques were made use of so as to characterize the surface structures of the electrodes. X-ray photoelectron spectroscopy studies confirmed that the deposit contains both Mo(V) and Mo(VI). The deposited films exhibited unique catalytic activity towards nitrite oxidation consistent with the change in peak characteristics. © 2012 Elsevier B.V. All rights reserved.
Description
Keywords
Carbon , Catalyst activity , Catalytic oxidation , Chlorine compounds , Chloroacetic acid , Crystal atomic structure , Cyclic voltammetry , Deposits , Dyes , Electrochemical deposition , Glass , Glass membrane electrodes , Gold deposits , Oxide films , Reduction , Scanning electron microscopy , Silver compounds , X ray photoelectron spectroscopy , Electrochemical formation , Electrochemical impedance measurements , Glassy carbon electrodes , Hydrogen molybdenum bronze , Mixed-valent , Potential zero charges , Solution composition , X-ray photoelectron spectroscopy studies , Molybdenum oxide