Nanoarchitectonics and properties of sol-gel-derived bioactive glasses containing maghemite@ZnO core-shell nanoparticles

dc.contributor.authorDeliormanlı A.M.
dc.contributor.authorALMisned G.
dc.contributor.authorTekin H.O.
dc.date.accessioned2024-07-22T08:01:02Z
dc.date.available2024-07-22T08:01:02Z
dc.date.issued2024
dc.description.abstractThis study comprehensively examined the structural, magnetic, hemocompatibility, and bioactivity properties of magnetic bioactive glass particles embedded with zinc oxide-coated superparamagnetic maghemite (γ-Fe2O3@ZnO) nanoparticles. Bioactive glass particles with varying concentrations of maghemite (2, 5, 10, and 20 wt%) were synthesized using the sol-gel method. The particles ranged in size from 6.83 μm to 14.5 μm, with size decreasing as maghemite content increased. The saturation magnetization values were 1.31 emu/g and 2.74 emu/g for the lowest and highest maghemite concentrations, respectively, indicating superparamagnetic behavior. Hydroxyapatite formation on the glass surfaces diminished with increased maghemite content, but hemocompatibility tests showed no significant hemolytic activity at a concentration of 0.5 mg/ml. The inclusion of γ-Fe2O3@ZnO nanoparticles significantly enhanced the gamma radiation attenuation properties of the bioactive glasses, particularly at higher maghemite concentrations. In conclusion, γ-Fe2O3@ZnO-enriched bioactive glasses exhibit promising potential for biomedical applications, offering a balance between magnetic functionality, bioactivity, and radiation shielding. Future research will focus on optimizing nanoparticle concentrations and surface modifications to enhance their multifunctionality. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.
dc.identifier.DOI-ID10.1007/s00339-024-07698-y
dc.identifier.issn09478396
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/11288
dc.language.isoEnglish
dc.publisherSpringer Science and Business Media Deutschland GmbH
dc.subjectBioactive glass
dc.subjectCore shell nanoparticles
dc.subjectHematite
dc.subjectII-VI semiconductors
dc.subjectMagnetite
dc.subjectMedical applications
dc.subjectNanomagnetics
dc.subjectProtective coatings
dc.subjectRadiation shielding
dc.subjectSaturation magnetization
dc.subjectSol-gel process
dc.subjectSol-gels
dc.subjectSuperparamagnetism
dc.subjectZinc coatings
dc.subjectZnO nanoparticles
dc.subjectGamma radiation attenuation
dc.subjectGlass particles
dc.subjectHaemocompatibility
dc.subjectMaghemites
dc.subjectMagnetic nanoarchitect
dc.subjectProperty
dc.subjectRadiation attenuation
dc.subjectSuperparamagnetic behavior
dc.subjectZinc oxide coating
dc.subjectZnO nanoparticles
dc.subjectGamma rays
dc.titleNanoarchitectonics and properties of sol-gel-derived bioactive glasses containing maghemite@ZnO core-shell nanoparticles
dc.typeArticle

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