Reduction of [Cp2*Mo2O5] by thioglycolic acid in an aqueous medium: Synthesis and structure of [{Cp*Mo(μ-SCH2COO)}2(μ-S)]

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dc.contributor.authorDemirhan F.
dc.contributor.authorTaban G.
dc.contributor.authorBaya M.
dc.contributor.authorDinoi C.
dc.contributor.authorDaran J.-C.
dc.contributor.authorPoli R.
dc.date.accessioned2024-07-22T08:23:42Z
dc.date.available2024-07-22T08:23:42Z
dc.date.issued2006
dc.description.abstractCompound [Cp2*Mo2O5] reacts with thioglycolic acid, HSCH2COOH, in an acidic (CF3COOH) mixed water-methanol solvent, to yield compound [{Cp*Mo(μ-SCH 2CO2)}2(μ-S)]. During this reaction, the thioglycolic acid acts as a reducing agent, as a ligand, and provides a sulfide ion for the Mo-S-Mo bridge. The molecular structure of the product can be described as containing two four-legged piano stools that share three legs. The Mo-Mo distance of 2.792(7) Å indicates metal-metal bonding, in agreement with the compound diamagnetism. © 2005 Elsevier B.V. All rights reserved.
dc.identifier.DOI-ID10.1016/j.jorganchem.2005.10.006
dc.identifier.issn0022328X
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/19658
dc.language.isoEnglish
dc.rightsAll Open Access; Green Open Access
dc.subjectChemical bonds
dc.subjectLigaments
dc.subjectMethanol
dc.subjectMolecular structure
dc.subjectMolybdenum
dc.subjectMolybdenum compounds
dc.subjectOrganic acids
dc.subjectReduction
dc.subjectSolvents
dc.subjectAlkylsulfido ligands
dc.subjectAqueous organometallic chemistry
dc.subjectC-S bond activation
dc.subjectCarboxilato ligands
dc.subjectOrganometallics
dc.titleReduction of [Cp2*Mo2O5] by thioglycolic acid in an aqueous medium: Synthesis and structure of [{Cp*Mo(μ-SCH2COO)}2(μ-S)]
dc.typeArticle

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