Highly conjugated isoindigo and quinoxaline dyes as sunlight photosensitizers for onium salt-photoinitiated cationic polymerization of epoxy resins

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dc.contributor.authorErcan B.T.
dc.contributor.authorGultekin S.S.
dc.contributor.authorYesil T.
dc.contributor.authorDincalp H.
dc.contributor.authorKoyuncu S.
dc.contributor.authorYagci Y.
dc.contributor.authorZafer C.
dc.date.accessioned2024-07-22T08:04:21Z
dc.date.available2024-07-22T08:04:21Z
dc.date.issued2022
dc.description.abstractIn this study, photoinitiated cationic polymerization of epoxy resins by photoinduced electron transfer reactions using four new chromophoric dyes, namely (3E)-1,1′-bis(2-ethylhexyl)-6,6′-dipyren-1-yl-3,3′-biindole-2,2′(1H,1′H)-dione (ISOIV), (3′E)-1,1′′′-diethyl-1′,1′′-bis(2-ethylhexyl)-1H,1′′′H-5,6′:3′,3′′:6′′,5′′′-quaterindole-2′,2′′(1′H,1′′H)-dione (ISOV), (3E)-6,6′-bis(9-ethyl-9H-carbazole-3-yl)-1-[(2R)-2-ethylhexyl]-1′-[(2S)-2-ethylhexyl]-3,3′-biindole-2,2′(1H,1′H)-dione (ISOVIII) and 3,3′-(6-bromokinoksalin-2,3-diyl)bis(9-ethyl-9H-carbazole) (TPDC6), and diphenyliodonium hexafluorophosphate (Ph2I+PF6−; DPI) under sunlight is reported. Upon irradiation, photoexcited dye forms an exciplex with DPI. Electron transfer reactions within the exciplex result in the formation of ionic species capable of initiating ring-opening polymerization of an epoxy resin. It is shown that among the investigated dyes, ISOVIII and TPDC6 exhibited higher initiation efficiency in accordance with their stronger electron-donating nature due to the presence of carbazole groups. © 2021 Society of Industrial Chemistry. © 2021 Society of Industrial Chemistry.
dc.identifier.DOI-ID10.1002/pi.6357
dc.identifier.issn09598103
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/12671
dc.language.isoEnglish
dc.publisherJohn Wiley and Sons Ltd
dc.subjectCationic polymerization
dc.subjectElectron transitions
dc.subjectPhotosensitizers
dc.subjectPolycyclic aromatic hydrocarbons
dc.subjectRing opening polymerization
dc.subjectElectron-transfer reactions
dc.subjectExciplexes
dc.subjectHexafluorophosphates
dc.subjectIonic species
dc.subjectIsoindigo
dc.subjectOnium salts
dc.subjectPhoto-induced electron transfer
dc.subjectPhotoinitiated cationic polymerization
dc.subjectPhotosensitiser
dc.subjectQuinoxalines
dc.subjectEpoxy resins
dc.titleHighly conjugated isoindigo and quinoxaline dyes as sunlight photosensitizers for onium salt-photoinitiated cationic polymerization of epoxy resins
dc.typeArticle

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