Targeted Singlet Oxygen Generation Using Different DNA-Interacting Perylene Diimide Type Photosensitizers
| dc.contributor.author | Dinçalp, H | |
| dc.contributor.author | Kizilok, S | |
| dc.contributor.author | Içli, S | |
| dc.date.accessioned | 2025-04-10T10:32:38Z | |
| dc.date.available | 2025-04-10T10:32:38Z | |
| dc.description.abstract | Singlet oxygen quantum yields (I broken vertical bar (Delta)) of different perylene diimides (PDIs) containing phenyl (PDI-Ph), pyrene (PDI-Pyr), and indole (PDI-In) units in bay positions of the ring were determined using 1,3-diphenylisobenzofuran (DPBF) method in toluene/methanol (99:1) system. Pyrene-substituted PDI were the most efficient singlet oxygen generator among the investigated photosensitizers with a quantum yield of I broken vertical bar (Delta) = 0.93 in toluene/methanol. Additionally, their binding affinities to G-quadruplex DNA structure were investigated by steady-state measurements. There were marked red shifts of absorbance bands for PDI-Pyr/DNA strand complexes with respect to the absorption maxima of DNA-free solution of PDI-Pyr in phosphate buffer at pH 6. | |
| dc.identifier.e-issn | 1573-4994 | |
| dc.identifier.issn | 1053-0509 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/38996 | |
| dc.language.iso | English | |
| dc.title | Targeted Singlet Oxygen Generation Using Different DNA-Interacting Perylene Diimide Type Photosensitizers | |
| dc.type | Article |