Novel metal(II) complexes with bidentate Schiff base ligand: Synthesis, spectroscopic properties and dye decolorization functions

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dc.contributor.authorKarakaya C.
dc.contributor.authorDede B.
dc.contributor.authorCicek E.
dc.date.accessioned2024-07-22T08:12:03Z
dc.date.available2024-07-22T08:12:03Z
dc.date.issued2016
dc.description.abstractThe bidentate Schiff base ligand 4-chloro-2-[1-(4-phenylphenyl)ethylideneamino]phenol and its mononuclear Co(II), Ni(II), Cu(II) and Zn(II) complexes have been synthesized. Ligand and metal complexes were characterized by elemental analyses, magnetic susceptibility, molar conductivity, 1H- and 13C-NMR, the Fourier transform infrared, UV-Vis, inductively coupled plasma optical emission spectrometry, and thermogravimetric-differential thermogravimetric studies. The results suggest that the mononuclear complexes have a metal to ligand mole ratio of 1:2 and the metal(II) ions are coordinated with the phenolic oxygen and imine nitrogen atoms. Octahedral structures are proposed for the complexes of the Schiff base ligand. Furthermore, the complexes were checked for their efficiency to decolorize the dye methylene blue. In our experiments we found that metal(II) complexes had an acceptable decolorization efficiency against the dye methylene blue.
dc.identifier.DOI-ID10.12693/APhysPolA.129.208
dc.identifier.issn05874246
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/15877
dc.language.isoEnglish
dc.publisherPolish Academy of Sciences
dc.rightsAll Open Access; Bronze Open Access
dc.subjectAromatic compounds
dc.subjectChelation
dc.subjectCobalt compounds
dc.subjectComplexation
dc.subjectCoordination reactions
dc.subjectEfficiency
dc.subjectInductively coupled plasma
dc.subjectLigands
dc.subjectMagnetic susceptibility
dc.subjectMetal complexes
dc.subjectMetals
dc.subjectNuclear magnetic resonance
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectOptical emission spectroscopy
dc.subjectSpectrometry
dc.subjectZinc compounds
dc.subjectDifferential thermogravimetric
dc.subjectFourier transform infra reds
dc.subjectInductively coupled plasma-optical emission spectrometry
dc.subjectMolar conductivities
dc.subjectMononuclear complexes
dc.subjectOctahedral structures
dc.subjectSchiff-base ligands
dc.subjectSpectroscopic property
dc.subjectSynthesis (chemical)
dc.titleNovel metal(II) complexes with bidentate Schiff base ligand: Synthesis, spectroscopic properties and dye decolorization functions
dc.typeConference paper

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