Thermoluminescence glow curve analysis and kinetic parameters of Eu doped Li2MoO4 ceramic phosphors

dc.contributor.authorSouadi G.
dc.contributor.authorOglakci M.
dc.contributor.authorKaynar U.H.
dc.contributor.authorCorrecher V.
dc.contributor.authorBenavente J.F.
dc.contributor.authorBulcar K.
dc.contributor.authorAyvacikli M.
dc.contributor.authorHiziroglu A.
dc.contributor.authorTopaksu M.
dc.contributor.authorCan N.
dc.contributor.authorKarali E.E.
dc.date.accessioned2024-07-22T08:04:13Z
dc.date.available2024-07-22T08:04:13Z
dc.date.issued2022
dc.description.abstractLiMoO4: x Eu ceramic phosphors with x = 0.5, 1, 2, 3, 5, and 7 mol% were synthesized using a gel combustion method. X-ray diffraction (XRD) measurements confirmed a rhombohedral structure (space group R3) of synthesized compounds. Following irradiation with 50 Gy beta dose, the sample doped with 5 mol% Eu exhibited the highest integrated thermoluminescence (TL) intensity. In order to evaluate dose-response, samples were irradiated with beta radiation for 10–1000 Gy. TL intensity with 1000 Gy dose without saturation yielded the highest integrated value. Different methods were employed to determine the number of peaks, the trap structure, and the kinetic parameters of the thermoluminescence glow curve of Eu doped Li2MoO4: the Hoogenstraaten method, the Booth-Bohun-Parfianovitch method, the initial rise method (IR), combined with the TM-Tstop experiment, various heating rates (VHR), and glow curve fitting with two different software packages. Based on the glow curve deconvolution obtained using both software packages, the component TL glow peaks present in the complex glow curve are composed of well-isolated nine overlapping glow peaks. Two software packages have shown quite similar activation energies and frequency factors. © 2022 Elsevier Ltd and Techna Group S.r.l.
dc.identifier.DOI-ID10.1016/j.ceramint.2022.03.218
dc.identifier.issn02728842
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/12606
dc.language.isoEnglish
dc.publisherElsevier Ltd
dc.subjectActivation energy
dc.subjectChemical analysis
dc.subjectCurve fitting
dc.subjectEuropium
dc.subjectKinetic parameters
dc.subjectLithium compounds
dc.subjectMolybdenum compounds
dc.subjectPhosphors
dc.subjectSoftware packages
dc.subjectThermoluminescence
dc.subjectChemical preparation
dc.subjectCurve analysis
dc.subjectGel-combustion method
dc.subjectGlow curve
dc.subjectGlow peaks
dc.subjectKinetics parameter
dc.subjectRare-earths
dc.subjectRhombohedral structures
dc.subjectSynthesised
dc.subjectX-ray diffraction measurements
dc.subjectRare earths
dc.titleThermoluminescence glow curve analysis and kinetic parameters of Eu doped Li2MoO4 ceramic phosphors
dc.typeArticle

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