Reduction of [CP2*Mo2O5] by thioglycolic acid in an aqueous medium
| dc.contributor.author | Demirhan, F | |
| dc.contributor.author | Taban, G | |
| dc.contributor.author | Baya, M | |
| dc.contributor.author | Dinoi, C | |
| dc.contributor.author | Daran, JC | |
| dc.contributor.author | Poli, R | |
| dc.date.accessioned | 2025-04-10T10:34:26Z | |
| dc.date.available | 2025-04-10T10:34:26Z | |
| dc.description.abstract | Compound [CP*2Mo2O5] reacts with thioglycolic acid, HSCH2COOH, in an acidic (CF3COOH) mixed water-methanol solvent, to yield compound [{Cp*Mo(mu-SCH2CO2)}(2)(mu-S)]. During this reaction, the thioglycolic acid acts as a reducing agent, as a ligand, and provides a sulfide ion for the Mo-S-Mo bridge. The molecular structure of the product can be described as containing two four-legged piano stools that share three legs. The Mo-Mo distance of 2.792(7) angstrom indicates metal-metal bonding, in agreement with the compound diamagnetism. (c) 2005 Elsevier B.V. All rights reserved. | |
| dc.identifier.e-issn | 1872-8561 | |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/40568 | |
| dc.language.iso | English | |
| dc.title | Reduction of [CP2*Mo2O5] by thioglycolic acid in an aqueous medium | |
| dc.type | Article |