Pyrene bisiminopyridine ligand and its zinc complex

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dc.contributor.authorAyadi A.
dc.contributor.authorBranzea D.
dc.contributor.authorDinçalp H.
dc.contributor.authorZouari N.
dc.contributor.authorEl-Ghayoury A.
dc.date.accessioned2024-07-22T08:12:06Z
dc.date.available2024-07-22T08:12:06Z
dc.date.issued2016
dc.description.abstractThe synthesis of a pyrene bisiminopyridine ligand L was successfully accomplished by condensation between 1-aminopyrene and 2,6-pyridinecarboxaldehyde. The complexation of L with zinc triflate afforded a neutral metal complex formulated as [Zn(H2O)LCF3SO3)2].2Et2O. In the complex, the ligand is coordinated to zinc(II) through its three nitrogen atoms which form a distorted octahedral environment together with three oxygen atoms, two from the triflate anions and one from aqua ligand. Both compounds have been characterized using NMR, elemental analysis, mass spectrometry, electronic absorption (UV-Vis) and infrared. Luminescence properties of these compounds show an emission maxima at 412 nm, indicating a pyrene monomer emission. © 2016 Taylor & Francis Group, LLC.
dc.identifier.DOI-ID10.1080/15421406.2015.1137386
dc.identifier.issn15421406
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/15913
dc.language.isoEnglish
dc.publisherTaylor and Francis Inc.
dc.subjectAbsorption spectroscopy
dc.subjectChelation
dc.subjectComplexation
dc.subjectFluorescence
dc.subjectLigands
dc.subjectLuminescence
dc.subjectMass spectrometry
dc.subjectMetal complexes
dc.subjectPyrene
dc.subjectUltraviolet visible spectroscopy
dc.subjectX ray diffraction
dc.subjectZinc
dc.subjectZinc compounds
dc.subjectElectronic absorption
dc.subjectEmission maxima
dc.subjectIminopyridine
dc.subjectLuminescence properties
dc.subjectMonomer emission
dc.subjectOctahedral environment
dc.subjectThree nitrogens
dc.subjectUV visible spectroscopy
dc.subjectCoordination reactions
dc.titlePyrene bisiminopyridine ligand and its zinc complex
dc.typeArticle

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