Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer
dc.contributor.author | Sözerli, SE | |
dc.contributor.author | Özen, A | |
dc.contributor.author | Kani, I | |
dc.contributor.author | Demir, D | |
dc.date.accessioned | 2025-04-10T10:31:37Z | |
dc.date.available | 2025-04-10T10:31:37Z | |
dc.description.abstract | A novel [Pb-2(mu-atrz)(2)(mu-CH3COO)(CH3COO)](n) (atrz = 3 amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2). | |
dc.identifier.issn | 1300-0527 | |
dc.identifier.uri | http://hdl.handle.net/20.500.14701/38080 | |
dc.language.iso | English | |
dc.title | Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer | |
dc.type | Article |