Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer
| dc.contributor.author | Sözerli S.E. | |
| dc.contributor.author | Özen A. | |
| dc.contributor.author | Kani I. | |
| dc.contributor.author | Demir D. | |
| dc.date.accessioned | 2024-07-22T08:17:15Z | |
| dc.date.available | 2024-07-22T08:17:15Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | A novel [Pb2(μ-atrz) 2(μ-CH3 COO)(CH 3 COO)]n (atrz = 3-amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecularstructure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2). © TÜBİTAK. | |
| dc.identifier.DOI-ID | 10.3906/kim-1308-19 | |
| dc.identifier.issn | 13000527 | |
| dc.identifier.uri | http://akademikarsiv.cbu.edu.tr:4000/handle/123456789/16997 | |
| dc.language.iso | English | |
| dc.publisher | TUBITAK | |
| dc.rights | All Open Access; Bronze Open Access | |
| dc.title | Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer | |
| dc.type | Article |