Synthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates [Cp*2M5VO17]- (M = Mo, W)
| dc.contributor.author | Özbek, HA | |
| dc.contributor.author | Kopar, EE | |
| dc.contributor.author | Demirhan, F | |
| dc.date.accessioned | 2025-04-10T10:33:39Z | |
| dc.date.available | 2025-04-10T10:33:39Z | |
| dc.description.abstract | A series of Lindqvist-type polyoxometalate (POM) compounds [Cat][Cp*2M5VO17] (M = Mo (1), W (2)) were obtained from Cp*2M2O5 and NaVO3 in a 1:10 molar ratio in an acidic aqueous-methanol medium ([Cat]: Bu4P+ (1a, 2a), Bu4N+ (1b, 2b), Ph4P+ (1c, 2c), and BuNC5H5+ (1d, 2d)). They have been structurally characterized by H-1 and P-31 NMR, FT-IR, TGA, ESI, and elemental analysis techniques which support the proposed structures. In antibacterial studies, Ph4P[Cp*2Mo5VO17] (1c) is the compound that shows the highest antimicrobial activity against both gram-positive and gram-negativebacteria. | |
| dc.identifier.e-issn | 1029-0389 | |
| dc.identifier.issn | 0095-8972 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/39897 | |
| dc.language.iso | English | |
| dc.title | Synthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates [Cp*2M5VO17]- (M = Mo, W) | |
| dc.type | Article |