Photopolymerization and characterization of vinyl imidazole based allyl derivative polymers; Cr3+ and Cd2+ metal adsorption and antibacterial studies

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dc.contributor.authorSaltan F.
dc.contributor.authorSaltan G.M.
dc.contributor.authorİlktaç R.
dc.contributor.authorÖzdokur K.V.
dc.date.accessioned2024-07-22T08:01:06Z
dc.date.available2024-07-22T08:01:06Z
dc.date.issued2024
dc.description.abstractA new type polymeric adsorbent, poly(allylphenol-co-hydroxyethyl methacrylate-co-vinyl imidazole) (PAHV), is synthesized in this study. 2-Hydroxyethyl methacrylate is used as complementary monomers along with 1-vinyl imidazole and allylphenol monomers. The photopolymerization method is preferred as a synthesis method and benzophenone is used as the photoinitiator. The effectiveness of the PAHV against bacterial species such as Escherichia coli and Staphylococcus aureus is investigated by the Clinical and Laboratory Standards Institute (CLSI) disk diffusion method. The inhibition areas of PA1H1V3 and PA1H1V1 derivatives against E. coli and S. aureus are measured as 25 mm ± 0.25 mm and 7 mm ± 0.1 mm; 20 mm ± 0.25 mm, and 5 mm ± 0.1 mm, respectively. Sorption efficiencies (%) at pH = 6 (selected optimum pH) for 100 μg/L Cd and Cr of the PA1H1V1, PA1H3V1, and PA1H1V3 derivatives are found to be 69.0 ± 2.7 and 58.3 ± 6.7, 66.8 ± 6.2 and 75.8 ± 5.5, and 97.2 ± 3.7 and 97.7 ± 3.2 (n = 3), respectively. Adsorption studies revealed that the PA1H1V3 polymer can be used as an alternative for the sorption of cadmium and chromium. The pseudo-second-order model and Langmuir isotherm model fits for both adsorption processes. The adsorption capacities obtained from the Langmuir isotherm model for chromium and cadmium sorption are 52.63 and 68.49 μg g−1, respectively. © 2024 Wiley Periodicals LLC.
dc.identifier.DOI-ID10.1002/app.55756
dc.identifier.issn00218995
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/11331
dc.language.isoEnglish
dc.publisherJohn Wiley and Sons Inc
dc.subjectAdsorption isotherms
dc.subjectCadmium
dc.subjectChromium
dc.subjectEscherichia coli
dc.subjectMonomers
dc.subjectPhotopolymerization
dc.subjectAdsorption studies
dc.subjectAllyl derivatives
dc.subjectAllylphenol
dc.subjectCr 3+
dc.subjectImidazol
dc.subjectLangmuir isotherm models
dc.subjectPhoto polymerization
dc.subjectProcessing technique
dc.subjectSynthesis and processing
dc.subjectSynthesis techniques
dc.subjectAdsorption
dc.titlePhotopolymerization and characterization of vinyl imidazole based allyl derivative polymers; Cr3+ and Cd2+ metal adsorption and antibacterial studies
dc.typeArticle

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