Syntheses and characterization of poly(iminophenol)s derived from 4-bromobenzaldehyde: Thermal, optical, electrochemical and fluorescent properties

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dc.contributor.authorKaya I.
dc.contributor.authorAvci A.
dc.contributor.authorGültekin O.
dc.date.accessioned2024-07-22T08:19:45Z
dc.date.available2024-07-22T08:19:45Z
dc.date.issued2012
dc.description.abstractSchiff base monomers [2-(4-bromobenzylideneamino)phenol and 2-(4-bromobenzylideneamino)-5-methylphenol] were synthesized by the condensation reaction of 4-bromobenzaldehyde with aromatic aminophenols. Then, the monomers were converted to their polyphenol derivatives by oxidative polycondensation reactions (OP) in an aqueous alkaline medium. The structures of the synthesized compounds were characterized by solubility tests, FT-IR, NMR, TG-DTA, DSC and SEC techniques. The HOMO-LUMO energy levels and electrochemical ( E'g ) and optical (Eg) band gaps were calculated from cyclic voltammetry (CV) and UV-Vis measurements, respectively. Cyclic voltammetry (CV) was used to determine the electrochemical oxidation-reduction characteristics. Optical properties were investigated by UV-Vis and fluorescence analyses. Solid state electrical conductivities were measured on polymer films by four point probe technique using a Keithley 2400 electrometer. The effects of electron-donating (?CH3) group at p-position of ?NH2 group in aminophenol on electrochemical and thermal properties were also discussed. Photoluminescence (PL) properties of the synthesized materials were determined in solution forms using different solvents. Fluorescence measurements were carried out in various concentrated solutions to determine the optimum concentrations to obtain the maximal PL intensities. © 2012 Chinese Chemical Society Institute of Chemistry, CAS Springer-Verlag Berlin Heidelberg.
dc.identifier.DOI-ID10.1007/s10118-012-1176-5
dc.identifier.issn02567679
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/17832
dc.language.isoEnglish
dc.publisherSpringer Verlag
dc.subjectCondensation reactions
dc.subjectElectric conductivity
dc.subjectElectrochemical oxidation
dc.subjectEnergy gap
dc.subjectFluorescence
dc.subjectMonomers
dc.subjectOptical properties
dc.subjectPolymer films
dc.subjectThermoanalysis
dc.subjectElectrical conductivity
dc.subjectElectrochemical oxidation reduction
dc.subjectFluorescence measurements
dc.subjectFour-point probe techniques
dc.subjectOxidative polycondensation
dc.subjectPhotoluminescence properties
dc.subjectSchiff Base polymers
dc.subjectSynthesized materials
dc.subjectCyclic voltammetry
dc.titleSyntheses and characterization of poly(iminophenol)s derived from 4-bromobenzaldehyde: Thermal, optical, electrochemical and fluorescent properties
dc.typeArticle

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