N-Heterocyclic carbene complexes of palladium(II) and rhodium(I) with pendant ferrocenylmethyl groups

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dc.contributor.authorDemirhan, F
dc.contributor.authorYildirim, Ö
dc.contributor.authorÇetinkaya, B
dc.date.accessioned2024-07-18T12:00:18Z
dc.date.available2024-07-18T12:00:18Z
dc.description.abstract1-Ferrocenylmethyl-3-benzylimidazolidinium iodide and 1-ferrocenylmethyl-3-( 2,4,6-trimethylbenzyl) imidazolidinium iodide were prepared in good yields by boiling, under reflux, a solution of (ferrocenylmethyl)trimethylammonium iodide and the appropriate N-alkyl-2-imidazoline in MeCN. From the 1-ferrocenylmethyl-3-ben-zylimidazolidinium iodide salt, N-heterocylic carbene complexes of Pd-II and Rh-I were synthesized by in situ deprotonation and subsequent trapping. The new compounds were characterized by C, H, N analyses, H-1- n. m. r., C-13-n.m.r. and by cyclic voltammetry. The n. m. r. properties of the complexes are compared with those of nonferrocenylated carbene derivatives. The c. v.'s of these compounds show a number of resolved redox processes, indicating that CH(2)Fc substituents are electronically isolated from the remaining molecular framework.
dc.identifier.issn0340-4285
dc.identifier.other1572-901X
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/7626
dc.language.isoEnglish
dc.publisherSPRINGER
dc.subjectION-BIOMOLECULE INTERACTIONS
dc.subjectSTABLE CARBENES
dc.subjectMETAL-COMPLEXES
dc.subjectSPECTROSCOPIC PROPERTIES
dc.subjectHOMOGENEOUS CATALYSIS
dc.subjectRUTHENIUM COMPLEXES
dc.subjectSUBSTITUENTS
dc.subjectMETATHESIS
dc.subjectCHEMISTRY
dc.subjectLIGAND
dc.titleN-Heterocyclic carbene complexes of palladium(II) and rhodium(I) with pendant ferrocenylmethyl groups
dc.typeArticle

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