Influence of Li dopants on thermoluminescence spectra of CaSO4 doped with Dy or Tm

dc.contributor.authorWang, Y
dc.contributor.authorCan, N
dc.contributor.authorTownsend, PD
dc.date.accessioned2024-07-18T12:00:16Z
dc.date.available2024-07-18T12:00:16Z
dc.description.abstractThermoluminescence emission spectra are presented for lithium doped variants of CaSO4:Dy or CaSO4:Tm dosimetry material. All three dopants (Li, Dy and Tm) variously introduce different changes in both the glow peak temperatures and the luminescence efficiency. In every case the emission signals display the line emission characteristic of the rare earth ions. At temperatures below similar to 50 K the relative peak intensities differ for Dy and Tm doped samples, and there are small temperature shifts between the Dy:Li and Tm:Li co-doped materials. Above room temperature the rare earth ions do not show peak temperature movements when co-doped with lithium. However they do influence the peak temperature by similar to 5 degrees C when they are the sole dopant. Inclusion of lithium dramatically moves the high temperature glow peak from similar to 200 degrees C down to 120 degrees C. All these changes are consistent with a single defect model in which the trapping sites and luminescence occur within the complexes formed of the rare earth ion, an intrinsic sulphate defect and lithium. The evidence and rationale for such a model are presented. There is discussion which suggests that such defect complexes are the norm in thermoluminescence. (C) 2011 Elsevier B.V. All rights reserved.
dc.identifier.issn0022-2313
dc.identifier.other1872-7883
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/7579
dc.language.isoEnglish
dc.publisherELSEVIER SCIENCE BV
dc.subjectELECTRON-SPIN-RESONANCE
dc.subjectTHERMOSTIMULATED LUMINESCENCE PHOSPHOR
dc.subjectTEMPERATURE DISTRIBUTION
dc.subjectSINGLE-CRYSTALS
dc.subjectTL
dc.subjectMECHANISMS
dc.subjectDEPENDENCE
dc.subjectCENTERS
dc.subjectLAG
dc.titleInfluence of Li dopants on thermoluminescence spectra of CaSO4 doped with Dy or Tm
dc.typeArticle

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