Synthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates [Cp*2M5VO17]- (M = Mo, W)

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dc.contributor.authorÖzbek, HA
dc.contributor.authorKopar, EE
dc.contributor.authorDemirhan, F
dc.date.accessioned2024-07-18T12:00:43Z
dc.date.available2024-07-18T12:00:43Z
dc.description.abstractA series of Lindqvist-type polyoxometalate (POM) compounds [Cat][Cp*2M5VO17] (M = Mo (1), W (2)) were obtained from Cp*2M2O5 and NaVO3 in a 1:10 molar ratio in an acidic aqueous-methanol medium ([Cat]: Bu4P+ (1a, 2a), Bu4N+ (1b, 2b), Ph4P+ (1c, 2c), and BuNC5H5+ (1d, 2d)). They have been structurally characterized by H-1 and P-31 NMR, FT-IR, TGA, ESI, and elemental analysis techniques which support the proposed structures. In antibacterial studies, Ph4P[Cp*2Mo5VO17] (1c) is the compound that shows the highest antimicrobial activity against both gram-positive and gram-negativebacteria.
dc.identifier.issn0095-8972
dc.identifier.other1029-0389
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/7914
dc.language.isoEnglish
dc.publisherTAYLOR & FRANCIS LTD
dc.subjectHIRSHFELD SURFACE-ANALYSIS
dc.subjectCRYSTAL-STRUCTURE
dc.subjectVIBRATIONAL INVESTIGATIONS
dc.subjectHYDROTHERMAL SYNTHESIS
dc.subjectFACE INTERACTIONS
dc.subjectOXO-CLUSTERS
dc.subjectLINDQVIST
dc.subjectEPOXIDATION
dc.subjectCOMPOUND
dc.subjectSUBSTITUTION
dc.titleSynthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates [Cp*2M5VO17]- (M = Mo, W)
dc.typeArticle

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