Enhanced Electrochemical Determination of Catechol and Hydroquinone Based on Pd Nanoparticles/Poly(Taurine) Modified Glassy Carbon Electrode

dc.contributor.authorKoçak, ÇC
dc.contributor.authorKoçak, S
dc.date.accessioned2024-07-18T11:51:18Z
dc.date.available2024-07-18T11:51:18Z
dc.description.abstractHere, Pd nanoparticles and poly(taurine) film was prepared on the glassy carbon electrode surface (Pd/Poly(TAU)/GCE) by the rapid electrochemical technique. The proposed composite surface was characterized by scanning electron microscopy(SEM), X-ray photoelectron spectroscopy(XPS) and electrochemical impedance spectroscopy(EIS). Enhanced electron transfer ability and higher electroactive surface area were achieved at Pd/Poly (TAU)/GCE as compared to the bare GCE and polymer film electrode. The new and highly stable Pd/Poly(TAU)/GCE was employed for the individual and simultaneous determination of hydroquinone and catechol which were environmentally toxic. Under the optimized conditions, HQ and CC were individually determined by using the differantial pulse voltammetry in the linear ranges of 0.008-100 mu M and 0.001-100 mu M with the detection limits of (LOD) 2.1 nM and 0.68 nM, respectively. In case of simultaneous determination, LODs were found as 10 nM and 0.88 nM for HQ and CC, respectively. The content of both analytes in the real sample analysis was evaluated in the river water and tap water successfully.
dc.identifier.issn1040-0397
dc.identifier.other1521-4109
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/4762
dc.language.isoEnglish
dc.publisherWILEY-V C H VERLAG GMBH
dc.subjectVOLTAMMETRIC DETERMINATION
dc.subjectSENSITIVE DETERMINATION
dc.subjectPASTE ELECTRODE
dc.subjectASCORBIC-ACID
dc.subjectURIC-ACID
dc.subjectNANOPARTICLES
dc.subjectGOLD
dc.subjectSENSOR
dc.subjectELECTROOXIDATION
dc.subjectFABRICATION
dc.titleEnhanced Electrochemical Determination of Catechol and Hydroquinone Based on Pd Nanoparticles/Poly(Taurine) Modified Glassy Carbon Electrode
dc.typeArticle

Files