Epoxidation of Cis-cyclooctene with Hydrogen Peroxide Catalyzed by Lindqvist Type Polyoxometalates
| dc.contributor.author | Avcı Özbek H. | |
| dc.contributor.author | Demirhan F. | |
| dc.date.accessioned | 2025-04-10T11:03:18Z | |
| dc.date.available | 2025-04-10T11:03:18Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | In our study, a method for the epoxidation of cis-cyclooctene was researched using a series of Lindqvist type POMs Cp*2MoxW6−xO17 (x=0, 2, 4, 6) and [Cp*MoxW6−xO18]− (x=0, 1, 5, 6) as a catalyst in the presence of 30 % H2O2 as a green oxidant. This catalytic system containing polyoxometalates and H2O2 has applied the most succesful system in obtaining epoxide product with excellent yields for cis-cyclooctene in acetonitrile at 55 °C. Maximum epoxidation efficiency of 99 % was observed under optimized conditions for Ph4P[Cp*MoW5O18] (2c). © 2023 Wiley-VCH GmbH. | |
| dc.identifier.DOI-ID | 10.1002/slct.202301019 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/44636 | |
| dc.publisher | John Wiley and Sons Inc | |
| dc.title | Epoxidation of Cis-cyclooctene with Hydrogen Peroxide Catalyzed by Lindqvist Type Polyoxometalates | |
| dc.type | Article |