Targeted singlet oxygen generation using different DNA-interacting perylene diimide type photosensitizers
| dc.contributor.author | Dinçalp H. | |
| dc.contributor.author | KIzIlok Ş. | |
| dc.contributor.author | Içli S. | |
| dc.date.accessioned | 2025-04-10T11:12:58Z | |
| dc.date.available | 2025-04-10T11:12:58Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Singlet oxygen quantum yields (ΦΔ) of different perylene diimides (PDIs) containing phenyl (PDI-Ph), pyrene (PDI-Pyr), and indole (PDI-In) units in bay positions of the ring were determined using 1,3-diphenylisobenzofuran (DPBF) method in toluene/methanol (99:1) system. Pyrene-substituted PDI were the most efficient singlet oxygen generator among the investigated photosensitizers with a quantum yield of Φ Δ=0.93 in toluene/methanol. Additionally, their binding affinities to G-quadruplex DNA structure were investigated by steady-state measurements. There were marked red shifts of absorbance bands for PDI-Pyr/DNA strand complexes with respect to the absorption maxima of DNA-free solution of PDI-Pyr in phosphate buffer at pH 6. © 2014 Springer Science+Business Media New York. | |
| dc.identifier.DOI-ID | 10.1007/s10895-014-1372-5 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/49711 | |
| dc.publisher | Springer New York LLC | |
| dc.title | Targeted singlet oxygen generation using different DNA-interacting perylene diimide type photosensitizers | |
| dc.type | Article |