Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

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dc.contributor.authorSözerli, SE
dc.contributor.authorÖzen, A
dc.contributor.authorKani, I
dc.contributor.authorDemir, D
dc.date.accessioned2024-07-18T11:54:07Z
dc.date.available2024-07-18T11:54:07Z
dc.description.abstractA novel [Pb-2(mu-atrz)(2)(mu-CH3COO)(CH3COO)](n) (atrz = 3 amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2).
dc.identifier.issn1300-0527
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/6121
dc.language.isoEnglish
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.subjectORGANIC FRAMEWORK MATERIALS
dc.subjectCRYSTAL-STRUCTURE
dc.subjectPB(II) COORDINATION
dc.subjectEMISSION PROPERTIES
dc.subjectLIGANDS
dc.subjectCOMPLEX
dc.subject2,2'-BIPYRIDINE
dc.subjectCARBOXYLATE
dc.subjectDICARBOXYLATE
dc.subjectCONSTRUCTION
dc.titleSynthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer
dc.typeArticle

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