Determination of synthesis conditions of medium, high, and overbased alkali calcium sulfonate
| dc.contributor.author | Besergil, B | |
| dc.contributor.author | Akin, A | |
| dc.contributor.author | Çelik, S | |
| dc.date.accessioned | 2024-07-18T12:01:04Z | |
| dc.date.available | 2024-07-18T12:01:04Z | |
| dc.description.abstract | This review covers a method for preparing an overbased detergent-dispersion additive called overbased calcium sulfonate solution (OBCSS) containing 38.9% (w/w) CaCO3, with a total base number (TBN) value of 436 mg KOH, starting from neutral calcium sulfonate solution (NCSS).(1,2) After the column conditions were optimized, the reaction parameters (P-CO2 and the amounts of Ca(OH)(2), water, and monoethanolamine (MEA)) were examined throughout the tests. The first product medium alkali calcium sulfonate solution (MACSS) with 8.5% (w/w) CaCO3 (TBN = 95 mg KOH/g) is obtained, but higher base values could not be reached. In the second stage, monoethanolamine is added to the feed as a promoter and high alkali calcium sulfonate solution (HACSS) containing 30.4% (w/w) CaCO3 with the value of TBN = 274 mg KOH/g is obtained. In the third stage of the study, targeted product OBCSS is obtained by using HACSS as a feedstock component instead of NCSS. | |
| dc.identifier.issn | 0888-5885 | |
| dc.identifier.uri | http://akademikarsiv.cbu.edu.tr:4000/handle/123456789/8169 | |
| dc.language.iso | English | |
| dc.publisher | AMER CHEMICAL SOC | |
| dc.title | Determination of synthesis conditions of medium, high, and overbased alkali calcium sulfonate | |
| dc.type | Article |