Synthesis and influence of ultrasonic treatment on luminescence of Mn incorporated ZnS nanoparticles

Simple item page
dc.contributor.authorCadis, AI
dc.contributor.authorMuresan, LE
dc.contributor.authorPerhaita, I
dc.contributor.authorMunteanu, V
dc.contributor.authorKarabulut, Y
dc.contributor.authorGuinea, JG
dc.contributor.authorCanimoglu, A
dc.contributor.authorAyvacikli, M
dc.contributor.authorCan, N
dc.date.accessioned2024-07-18T12:06:03Z
dc.date.available2024-07-18T12:06:03Z
dc.description.abstractManganese (Mn) doping of ZnS phosphors was achieved by precipitation method using different ultrasound (US) maturation times. The structural and luminescence properties of the samples were carried out by means of X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), photoluminescence (PL), and cathodoluminescence (CL). The real amount of manganese incorporated in ZnS lattice was calculated based on ICP-OES results. According with XRD patterns, the phase structure of ZnS:Mn samples is cubic. EDS spectra reveal deviations of the Mn dopant concentration from the target composition. Both 300 K PL and CL emission spectra of the Mn doped ZnS phosphors display intense orange emission at 590 and 600 nm, respectively, which is characteristic emission of Mn ion corresponding to a T-4(1) -> (6)A(1) transition. Both PL and CL spectra confirmed manganese is substitutionally incorporated into the ZnS host as Mn2+. However, it is suggested that the origin of broad blue emission around 400 nm appeared in CL is due to the radiative recombination at deep level defect states in the ZnS. The ultrasound treatment at first enhances the luminescent intensity by similar to 3 times in comparison with samples prepared by classical way. This study gives rise to an optimization guideline, which is extremely demanded for the development of new luminescent materials. (C) 2017 Elsevier B.V. All rights reserved.
dc.identifier.issn0925-3467
dc.identifier.other1873-1252
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/10165
dc.language.isoEnglish
dc.publisherELSEVIER SCIENCE BV
dc.subjectPHOTOLUMINESCENCE PROPERTIES
dc.subjectQUANTUM DOTS
dc.subjectDOPED CDS
dc.subjectOPTICAL-PROPERTIES
dc.subjectAQUEOUS ROUTE
dc.subjectNANOCRYSTALS
dc.subjectTEMPERATURE
dc.subjectGEL
dc.titleSynthesis and influence of ultrasonic treatment on luminescence of Mn incorporated ZnS nanoparticles
dc.typeArticle

Files

Collections

Web of Science Koleksiyonu