Cyclopentadienylmolybdenum(VI) and molybdenum(V) oxo chemistry: New synthetic and structural features
| dc.contributor.author | Saurenz D. | |
| dc.contributor.author | Demirhan F. | |
| dc.contributor.author | Richard P. | |
| dc.contributor.author | Poli R. | |
| dc.contributor.author | Sitzmann H. | |
| dc.date.accessioned | 2025-04-10T11:18:13Z | |
| dc.date.available | 2025-04-10T11:18:13Z | |
| dc.date.issued | 2002 | |
| dc.description.abstract | Convenient syntheses for Cp, Cp*, and related cyclopentadienyl derivatives (4Cp = C5HiPr4i CP‴ = C5H2tBU3-1,2,4) of formula [(Ring)2Mo2O5] are described. Compound [Cp2Mo2O5] was produced in good yields by the rapid oxidation of red [CpMoO2]4 with PhIO in CH2Cl2. [Cp*2Mo2O5] was obtained by CH3COOH acidification of aqueous solutions of [Cp*MoO3]-Na+, the latter being generated in a single step from [Cp*MoCl4] and more than 5 equiv. of aqueous NaOH in air. Minor quantities of [Cp*MoO2]2 were also isolated from this reaction, although the formation of this by-product may be reduced by using a two-step basic hydrolysis procedure. Extension of the latter strategy also allowed the preparation of [4Cp2Mo2O5], [Cp‴2Mo2O5], and [4CpMoO2Cl] in good yields, in addition to the by-product [Cp‴MoO2]2. X-ray structures are reported for compounds [4Cp2Mo2O5], [Cp‴2Mo2O5], [Cp*MoO2]2, [Cp‴MoO2]2, and [4CpMoO2Cl]. © Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002. | |
| dc.identifier.DOI-ID | 10.1002/1099-0682(200206)2002:6<1415 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/53290 | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.title | Cyclopentadienylmolybdenum(VI) and molybdenum(V) oxo chemistry: New synthetic and structural features | |
| dc.type | Article |