Dinuclear N-heterocyclic carbene silver complexes: Synthesis, luminescence and catalytic studies
| dc.contributor.author | Demir Atlı D. | |
| dc.contributor.author | Gülle S. | |
| dc.date.accessioned | 2025-04-10T11:07:22Z | |
| dc.date.available | 2025-04-10T11:07:22Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | A new dibenzimidazole compound (1) and three dibenzimidazolium salts (2a-2c) were prepared. Reactions of these salts with silver(I) oxide in methanol led to dinuclear N-heterocyclic carbene silver complexes (3a-3c). All of the compounds were characterized by 1H NMR, 13C NMR and elemental analyses. Molecular weights of the silver complexes were confirmed by MALDI-TOF mass spectrometry. Preliminary catalytic studies using all the silver complexes were performed on three-component coupling reaction of p-formaldehyde, piperidine and phenylacetylene. Complexes 3a and 3c exhibited good catalytic activities under neat conditions. The silver complexes showed luminescence properties in CH3CN at room temperature. © 2018 Elsevier B.V. | |
| dc.identifier.DOI-ID | 10.1016/j.molstruc.2018.11.053 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.14701/47342 | |
| dc.publisher | Elsevier B.V. | |
| dc.title | Dinuclear N-heterocyclic carbene silver complexes: Synthesis, luminescence and catalytic studies | |
| dc.type | Article |