Reduction of [CP2*Mo2O5] by thioglycolic acid in an aqueous medium

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dc.contributor.authorDemirhan, F
dc.contributor.authorTaban, G
dc.contributor.authorBaya, M
dc.contributor.authorDinoi, C
dc.contributor.authorDaran, JC
dc.contributor.authorPoli, R
dc.date.accessioned2024-07-18T12:02:40Z
dc.date.available2024-07-18T12:02:40Z
dc.description.abstractCompound [CP*2Mo2O5] reacts with thioglycolic acid, HSCH2COOH, in an acidic (CF3COOH) mixed water-methanol solvent, to yield compound [{Cp*Mo(mu-SCH2CO2)}(2)(mu-S)]. During this reaction, the thioglycolic acid acts as a reducing agent, as a ligand, and provides a sulfide ion for the Mo-S-Mo bridge. The molecular structure of the product can be described as containing two four-legged piano stools that share three legs. The Mo-Mo distance of 2.792(7) angstrom indicates metal-metal bonding, in agreement with the compound diamagnetism. (c) 2005 Elsevier B.V. All rights reserved.
dc.identifier.issn0022-328X
dc.identifier.other1872-8561
dc.identifier.urihttp://akademikarsiv.cbu.edu.tr:4000/handle/123456789/8570
dc.language.isoEnglish
dc.publisherELSEVIER SCIENCE SA
dc.subjectCYCLOPENTADIENYL MOLYBDENUM DIMERS
dc.subjectSULFIDO LIGANDS
dc.subjectTHIOLATE COORDINATION
dc.subjectCRYSTAL-STRUCTURES
dc.subjectCOMPLEXES
dc.subjectOXIDATION
dc.subjectCHEMISTRY
dc.subjectDINUCLEAR
dc.subjectDESULFURIZATION
dc.subject(C5ME5)(2)MO2O5
dc.titleReduction of [CP2*Mo2O5] by thioglycolic acid in an aqueous medium
dc.typeArticle

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